CH

ZHANG JunliangOrganic Chemistry, Professor

E-mail:Junliangzhang@fudan.edu.cn
Office Location:Room A7001, Chemistry Building, Department of Chemistry, Fudan University 2005 Songhu Road, Yangpu District, Shanghai 200438, China
Tel:86-21-31249180 86-21-31249181

  • Research Interests

  • Academic Appointments

  • Prizes and awards

  • Biography

  • Teaching

  • Key Publications

  • developing new synthetic reactions of conjugated enynes and small rings.

  • Design and synthesis of novel chiral ligands and their applications in asymmetric catalysis.

  • Developing novel catalyst for polymerization.

  • Member of Chinese Chemical Society

  • 2014, National Science Fund for Distinguished Young Scholars

  • 2014, ACP-Lectureship Award

  • 2013, Distinguished Lectureship Award

  • 2012, Synfacts/Synlett/Synthesis Journal Award

  • 2009, Chinese Chemical Society for young Scientists

  • 1993.9-1997.6            BSc, Department of Chemistry, Tianjing University

  • 1997.9-2002.6            Ph.D., Shanghai Institute of Organic Chemistry (SIOC), CAS, Shanghai, China

  • 2002.7-2003.9            Research Chemist, SIOC

  • 2003.10-2004.12           Humboldt Fellow, Institute of Organic Chemistry, University of Cologne, Germany

  • 2005.2-2006.10           Postdoc, Department of Chemistry, University of Chicago, USA

  • 2006.12-2017.9           Professor and Vice Dean, School of Chemistry and Molecular Engineering, East China Normal University

  • 2017.10-               Professor, Department of Chemistry, Fudan University

    Organometallic Chemistry

  1. B. Ma, Z. Chu, B. Huang, Z. Liu, L. Liu*, J. Zhang* Highly para-selective C-H Alkylation of Benzene Derivatives with 2,2,2-Trifluoroethyl α-Aryl-α-diazoesters. Angew. Chem. Int. Ed., 2017, 56, 2749-2753.

  2. C.-Z. Zhu, J.-J. Feng*, J. Zhang* Rhodium(I)-Catalyzed Intermolecular Aza-[4+3] Cycloaddition of Vinyl Aziridines and Dienes: Atom-Economical Synthesis of nantiomerically Enriched Functionalized Azepines. Angew. Chem. Int. Ed., 2017, 56, 1351–1355

  3. Z. Yu, Y. Li, J. Shi, B. Ma, L. Liu, J. Zhang* (C6F5)3B -Catalyzed Highly Chemoselective and Ortho-selective C-H Bond Functionalization of Phenols Oriented by Hydrogen Bonds. Angew. Chem. Int. Ed., 2016, 55, 14807-14811.

  4. P. Chen, Z. Yue, J. Zhang, X. Lv, L. Wang, J. Zhang* Phosphine-Catalyzed Asymmetric Umpolung Addition of Trifluoromethyl Ketimines to Morita–Baylis–Hillman Carbonates. Angew. Chem. Int. Ed. 2016, 55, 13316-13320.

  5. T.-Y. Lin, C.-Z. Zhu, P. Zhang, Y. Wang, H.-H. Wu, J.-J. Feng*, J. Zhang* Regiodivergent Intermolecular [3+2] Cycloadditions of Vinyl Aziridines and Allenes: Stereospecific Synthesis of Chiral Pyrrolidines. Angew. Chem. Int. Ed.2016, 55, 10844-10848.

  6. Z.-M. Zhang, B. Xu, S. Xu, H.-H. Wu, J. Zhang* Diastereo- and Enantioselective Copper(I)-Catalyzed Intermolecular [3+2] Cycloaddition of Azomethine Ylides with β-Trifluoromethyl β,β-Disubstituted Enones. Angew. Chem. Int. Ed. 2016, 55, 6324–6328.

  7. J.-J. Feng, T.-Y. Lin, C.-Z. Zhu, H. Wang, H.-H. Wu, J. Zhang* The Divergent Synthesis of Nitrogen Heterocycles by Rhodium(I)-Catalyzed Intermolecular Cycloadditions of Vinyl Aziridines and Alkynes. J. Am. Chem. Soc. 2016, 138, 2178-2181.

  8. L. Liu*, J. Zhang* Gold-catalyzed transformations of α-diazocarbonyl compounds: selectivity and diversity. Chem. Soc. Rev.2016, 45, 506-516.

  9. W. Li, J. Zhang* Recent developments in the synthesis and utilization of chiral β-aminophosphine derivatives as catalysts or ligands. Chem. Soc. Rev. 2016, 45, 1657-1677.

  10. J.-J. Feng, T.-Y. Lin, H.-H. Wu, J. Zhang* Modular Access to the Stereoisomers of Fused Bicyclic Azepines: Rhodium-Catalyzed Intramolecular Stereospecific Hetero-[5+2] Cycloaddition of Vinyl Aziridines and Alkenes. Angew. Chem. Int. Ed.2015, 54, 15854-15858.

  11. W. Zhou, X. Su, M. Tao, C. Zhu, Q. Zhao*, J. Zhang* A Novel Chiral Sulfinamide Bisphosphine Catalysts: Design, Synthesis, and Application in Highly Enantioselective Inter-molecular Cross Rauhut–Currier Reactions. Angew. Chem. Int. Ed.2015, 54, 14853-14857

  12. Y. Wang, P. Zhang, D. Qian, J. Zhang* Highly Regio-, Diastereo-, and Enantioselective Gold(I)-Catalyzed Intermolecular Annulations with N-Allenamides at the Proximal C=C Bond. Angew. Chem. Int. Ed. 2015, 54, 14849-14852 (Cover paper).

  13. L. Zhou, B. Xu, J. Zhang* Metal-free Dehydrogenative Diels-Alder Reactions of 2-Methyl, 3-Aryl-methyl-indoles and Dienophiles:A Rapid Access to Tetrahydrocarbazoles, Carbazoles and Heteroacenes. Angew. Chem. Int. Ed.2015, 54, 9092-9096.

  14. X. Su, W. Zhou, Y. Li, J. Zhang* Design, Synthesis, and Application of a Chiral Sulfinamide Phosphine Catalyst for the Enantioselective Intramolecular Rauhut–Currier Reaction. Angew. Chem. Int. Ed.2015, 54, 6874-6877.

  15. J.-J. Feng, T.-Y. Lin, H.-H. Wu, J. Zhang* Transfer of Chirality in the Rhodium-Catalyzed Intramolecular Formal Hetero-[5 + 2] Cycloaddition of Vinyl Aziridines and Alkynes: Stereoselective Synthesis of Fused Azepine Derivatives. J. Am.Chem. Soc. 2015, 137, 3787-3790.

  16. D. Qian, J. Zhang* Gold-Catalyzed Cyclopropanation Reactions by Carbenoid Precursor Toolbox. Chem. Soc. Rev.2015, 44, 677-698. (Cover paper)

  17. D. Qian, H. Hu, F. Liu, B. Tang, W. Ye, Y. Wang, J. Zhang* Gold(I)-Catalyzed Highly Diastereo- and Enatioselective Alkyne Oxidation/Cyclopropanation of 1,6-Enynes. Angew. Chem. Int. Ed.2014, 53, 13751-13755.

  18. L. Zhou, M. Zhang, W. Li, J. Zhang* Furan-Based o-Quinodimethanes by Gold-Catalyzed Dehydrogenative Heterocyclization of 2-(1-Alkynyl)-2-alken-1-ones: A Modular Entry to 2,3-Furan Fused Carbocycles. Angew. Chem. Int. Ed.2014, 53, 6542-6545.

  19. Z. Yu, B. Ma, M. Chen, H.-H. Wu, L. Liu*, J. Zhang* Highly Site-selective Direct C-H Bond Functionalization of Phenols with α-Aryl-α-Diazoacetates and Diazooxindoles via Gold Catalysis. J. Am. Chem. Soc.2014, 136, 6904-6907.

  20. Z.-M. Zhang, P. Chen, W. Li, Y. Niu, X. Zhao, J. Zhang* A New Type of Chiral Sulfinamide Monophosphine Ligands: Stereodivergent Synthesis and Application in Enantioselective Gold(I)-Catalyzed Cycloaddition Reactions. Angew. Chem. Int. Ed. 2014, 53, 4350-4354.

  21. H. Qian, X. Yu, J. Zhang*, J. Sun* Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes. J. Am. Chem. Soc. 2013, 135, 18020–18023.

  22. J.-J. Feng‚ J. Zhang* An Atom-Economic Synthesis of Bicyclo[3.1.0]hexanes by Rhodium N-Heterocyclic Carbene-Catalyzed Diastereoselective Tandem Hetero-[5 + 2] Cycloaddition/Claisen Rearrangement Reaction of Vinylic Oxiranes with Alkynes. J. Am. Chem. Soc.2011133‚ 7304–7307.

  23. F. Liu‚ D. Qian‚ L. Li‚ X. Zhao‚ J. Zhang* Diastereo- and Enantioselective Gold(I)-Catalyzed Intermolecular Tandem Cyclization/[3+3]Cycloadditions of 2-(1-Alkynyl)-2-alken-1- ones with Nitrones. Angew. Chem. Int. Ed. 201049‚ 6669-6672.

  24. L. Liu‚ J. Zhang* Selectivity-Control in Lewis-acid Catalyzed Regiodivergent Tandem Cationic Cyclization/Ring Expansion Terminated by Pinacol Rearrangement. Angew. Chem. Int. Ed. 200948‚ 6093-6096.

  25. F. Liu‚ Y. Yu‚ J. Zhang* Highly Substituted Furo[3‚4-d][1‚2]oxazines: Gold-Catalyzed Regiospecific and Diastereoselective 1‚3-Dipolar Cycloaddition of 2-(1-Alkynyl)-2-alken-1-ones with Nitrones. Angew. Chem. Int. Ed. 200948‚ 5505 –5508.

  26. Y. Xiao, J. Zhang* Tetrasubstituted Furans by a PdII-Catalyzed Three- Component Michael Addition/Cyclization/Cross-Coupling Reaction. Angew. Chem.‚ Int. Ed.200847‚ 1903-1906.

Address: Chemistry Building, Department of Chemistry, Fudan University
2005 Songhu Road, Yangpu District, Shanghai 200438, China  Tel: 86-21-31242791
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