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包信和物理化学,教授,博士生导师

电子邮箱:xhbao@fudan.edu.cn

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  •   主要从事表面化学与催化基础和应用研究。发现次表层氧对金属银催化选择氧化的增强效应,揭示了次表层结构对表面催化的调变规律,制备出具有独特低温活性和选择性的纳米催化剂,解决了重整氢气中微量CO造成燃料电池电极中毒失活的难题。发现了纳米催化体系的协同限域效应,研制成碳管限域的纳米金属铁催化剂和纳米Rh-Mn催化剂,使催化合成气转化的效率成倍提高。在甲烷活化方面,以分子氧为氧化剂,实现了甲烷在80 oC条件下直接高效氧化为甲醇的反应;创制了Mo/MCM-22催化剂,使甲烷直接芳构化制苯的单程收率大幅度提高。





  1. Xiaoguang Guo, Guangzong Fang, Gang Li, Hao Ma, Hongjun Fan, Liang Yu, Chao Ma, Xing Wu, Dehui Deng, Mingming Wei, Dali Tan, Rui Si, Shuo Zhang, Jianqi Li, Litao Sun, Zichao Tang, Xiulian Pan, Xinhe Bao*,Direct, Nonoxidative Conversion of Methane to Ethylene, Aromatics, and Hydrogen, Science,344(2014)616-619

  2. Wei Chen, Zhongli Fan, Lin Gu, Xinhe Bao* and Chunlei Wang, Enhanced capacitance of manganese oxide via confinement inside carbon nanotubes, Chem. Commun., 46(2010)3905-2907

  3. Qiang Fu, WeiXue Li, Yunxi Yao, Hongyan Liu, HaiYan Su, Ding Ma, XiangKui Gu,Limin Chen, Zhen Wang, Hui Zhang, Bing Wang, Xinhe Bao*, Interface-Confined Ferrous Centers for Catalytic Oxidation, Science, 328(2010)1141-1144

  4. Dehui Deng, Xiulian Pan*, Hui Zhang, Qiang Fu, Dali Tan, and Xinhe Bao*, Freestanding graphene via thermal splitting of silicon carbide granules, Advanced materials, 22(2010)2168-2171

  5. Lijun Gu, Ding Ma, Songdong Yao, Chunlei Wang, Wenjie Shen and Xinhe Bao*, Structured Zeolites Catalysts with Hierarchical Channel Structure,Chem. Commun., 46(2010)1733-1735

  6. Z. Yin, D. Ma, X. Bao*,Emulsion-assisted synthesis of monodisperse binary metal nanoparticles, Chem. Commun., (2010)(8)1344-1346

  7. Shujing Guo, Xiulian Pan, Haili Gao, Zhiqiang Yang, Jijun Zhao, Xinhe Bao*,Probing the electronic effect of carbon nanotube in catalysis: NH3 synthesis over Ru nanoparticles,Chem Eur J, 2010, 16: 5379–5384

  8. Lijun Gu, Ding Ma, Songdong Yao, Xiumei Liu, Xiuwen Han, Wenjie Shen, and Xinhe Bao*,Template-Synthesized Porous Silicon Carbide as an Effective Host for Zeolite Catalysts,CHEMISTRY-A EUROPEAN JOURNAL, 15(2009)13449-13455 

  9. Yafang Fan, Zengjian An, Xiulian Pan, Xiumei Liu and Xinhe Bao*,Quinone tailored selective oxidation of methane over palladium catalyst with molecular oxygen as an oxidant,Chem. Commun., (2009)7488-7490 

  10. Jianqin Zhuang, Xiuwen Han, Xinhe Bao* , Ulrich Mueller,In-situ 13C MAS NMR investigation of solvent effect on the formation of phenylacetaldehyde over TS-1 zeolite,J. Catal., 267(2009)177-180

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