师资队伍
贺鹤勇
物理化学
教授，博士生导师
heyonghe@fudan.edu.cn
上海市杨浦区淞沪路2005号 复旦大学江湾校区化学楼 A2007室
021-31243916
研究兴趣
C1分子及低碳烃的催化转化
固体核磁共振等技术研究催化剂结构和催化反应机理
酸催化
多相催化加氢和手性加氢
苯羟基化制苯酚催化剂研究
学术任职
《催化学报》编委
《波谱学报》编委
中国化学会催化专业委员会委员
中国物理学会波谱学专业委员会委员
上海市化学化工学会副理事长
学习工作经历
1980.10-1984.6 复旦大学化学系本科，获得理学学士学位
1984.6-1989.6 复旦大学化学系助教
1989.6-1990.6 英国伦敦帝国理工学院化学系访问学者
1990.7-1993.9 英国剑桥大学化学系研究生，获得理学博士学位
1993.10-1997.7 英国剑桥大学化学系固体核磁共振实验室Manager
1997.8-2000.3 英国利物浦大学化学系Leverhulme催化中心Principal Scientist
2000.4起 复旦大学化学系教授
授课情况
固体核磁共振及其在结构表征和催化反应机理研究中的应用
物理化学实验
代表性论文或专著
X. Chen, D.F. Huang, L.L. He, L. Zhang, Y.H. Ren, X.Y. Chen, B. Yue, H.Y. He. The effect of adsorbed water molecules on the surface acidity of niobium and tantalum oxides studied by MAS NMR. J. Phys. Chem. C. 125, 9330-9341 (2021).
C. Liu, J.J. Su, S. Liu, H.B. Zhou, X.H. Yuan, Y.C. Ye, Y. Wang, W.Q. Jiao, L. Zhang, Y.Q. Lu, Y.D. Wang, H.Y. He, Z.K. Xie. Insights into the key factor of zeolite morphology on selective conversion of syngas to light aromatics over Cr2O3/ZSM-5 catalyst. ACS. Catal. 10, 15227-15237 (2020).
J.F. Zhou, L. Ye, D.F. Huang, M.Y. Wang, Y.H. Ren, B. Yue, H.Y. He. The synergy of modulated surface polarity and oxygen vacancy for CO2 to methanol over Zn(δ−)-Ti(δ+)Ovacancy. J. Energy Chem. 56, 449-454 (2020).
Y.N. Wu, X. Chen, D.F. Huang, L. Zhang, Y.H. Ren, G.F. Tang, X.Y. Chen, B. Yue, H.Y. He. The study on acidity of sulfated CuO layers grown by surface reconstruction of Cu2O exposed with specific facets. Catal. Sci. & Tech. 10, 3985-3993 (2020).
X. Li, Y.H. Ren, Z.W. Weng, B. Yue, H.Y. He. Stabilization of high-valent Cu3+ in a Keggin-type polyoxometalate. Chem. Commun. 56, 2324-2327 (2020).
Y.N. Wu, D.F. Huang, Y.Y. Fu, L. Zhang, S.X. Liu, G.F. Tang, Y.H. Ren, L. Ye, X.Y. Chen, B. Yue, H.Y. He.Investigation on surface acidic properties of the facet-dependent sulfated Cu2O solids by 31P MAS NMR. Chem.-A Eur J. 25, 14771-14774 (2019).
Y.N. Wu, Y.Y. Fu, L. Zhang, Y.H. Ren, X.Y. Chen, B. Yue H.Y. He. The study of oxygen vacancies on different facets of anatase TiO2. Chin. J. Chem. 37, 922-928 (2019).
X.Y. Gao, X.Y. Chen, Z.H. Li, H.Y, He. Direct synthesis of in-situ chirally modified palladium nanocrystals without capping agents and their application in heterogeneous enantioselective hydrogenations. ACS Catal. 9, 6100-6110 (2019).
Y.Y. Fu, L. Zhang, B. Yue, X.Y. Chen, H.Y. He. Simultaneous characterization of solid acidity and basicity of metal oxide catalysts via solid state NMR technique. J. Phys. Chem. C 122, 24094-24102 (2018).
N. Su, X.Y. Gao, X.Y. Chen, B. Yue, H.Y He. The enantioselective hydrogenation of acetophenone over Pd concave tetrahedron nanocrystals affected by the residual adsorbed capping agent polyvinylpyrrolidone (PVP). J. Catal. 367, 244-251 (2018).
Y.C. Hu, B. Guo, Y.Y. Fu, Y.H. Ren, G.F. Tang, X.Y. Chen, B. Yue, H.Y. He. Facet-dependent acidic and catalytic properties of sulfated titania solid superacids. Chem. Commun. 51, 14219-14222 (2015).
L.P. Qian, W.J. Cai, L. Zhang, L. Ye, J. Li, M. Tang, B. Yue, H.Y. He. The promotion effect of hydrogen spillover on CH4 reforming with CO2 over Rh/MCF catalysts. Appl. Catal. B: Environ. 164, 168-175 (2015).
Y. Wang, N. Su, L. Ye, Y.H. Ren, X.Y. Chen, Y.J. Du, Z.H. Li, B Yue, S.C. Tsang, Q. Chen, H.Y He. Tuning enantioselectivity in asymmetric hydrogenation of acetophenone and its derivatives via confinement effect over free-standing mesoporous Pd network catalysts. J. Catal. 313, 113-126 (2014).
L.P. Qian, Y. Ren, H. Yu, Y. Wang, B. Yue, H.Y. He. Controlled atmosphere 13C and 1H MAS NMR study of reforming route of methane with carbon dioxide over Rh/SBA-15. Appl. Catal. A: Gen. 401, 114-118 (2011).
X.Y. Chen, M.H. Qiao, S.H. Xie, K.N. Fan, W.Z. Zhou, H.Y. He. Icositetrahedra of zeolite analcime with a polycrystalline core: a reversed crystal growth route. J. Am. Chem. Soc. 129, 13305-13312 (2007).
