师资队伍
张俊良
有机化学
教授，博士生导师
junliangzhang@fudan.edu.cn
上海市杨浦区淞沪路2005号 复旦大学江湾校区化学楼 A7001室
021-31249180/021-31249181
研究兴趣
共轭烯炔化学
小环化学
金催化
不对称催化
新催化剂的设计与开发
学术任职
上海市绿色化学与化工过程绿色化重点实验室‚第二届学术委员会委员
中国化学会永久会员
获奖情况
2014年获国家自然科学基金委杰出青年科学基金
2012年获Thieme Chemistry Journal Award
2009年获中国化学会青年化学家奖
学习工作经历
1993.09-1997.06 天津大学化学系本科，获得理学学士学位
1997.09-2002.06 中科院上海有机所，获得理学博士学位（导师：麻生明院士）
2002.07-2003.09 中科院上海有机所，助教
2003.10-2005.01 德国科隆大学化学系，博士后（洪堡学者奖学金）
2005.02-2006.10 美国芝加哥大学化学系，博士后
2006.12-2017.08 华东师范大学化学与分子工程学院教授，副院长
2017.09起 复旦大学化学系教授
代表性论文或专著
Y. Liu, W. Li, J. Zhang* Chiral ligands designed in China. Natl. Sci. Rev. 2017, 4, 326–358.
Y. Wang, P.-C. Zhang, X. Di, Q. Dai, Z.-M. Zhang, J. Zhang* Gold-Catalyzed Asymmetric Intramolecular Cyclization of N-Allenamides for the Synthesis of Chiral Tetrahydrocarbolines. Angew. Chem. Int. Ed. 2017, 56, 15905–15909.
S. Xu, Z.-M. Zhang, B. Xu, B. Liu, Y. Liu*, J. Zhang* Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions. J. Am. Chem. Soc. 2018, 140, 2272–2283.
L. Wang, M. Chen, P.-C. Zhang, W. Li, J. Zhang* Palladium/PC-Phos-Catalyzed Enantioselective Arylation of General Sulfenate Anions: Scope and Synthetic Applications. J. Am. Chem. Soc. 2018, 140, 3467–3473.
Z.-M. Zhang, B. Xu, Y. Qian, L. Wu, Y. Wu, L. Zhou, Y. Liu, J. Zhang* Palladium-Catalyzed Enantioselective Reductive Heck Reactions: Convenient Access to 3,3-Disubstituted 2,3-Dihydrobenzofuran. Angew. Chem. Int. Ed. 2018, 57, 10373–10377.
H. Wang, L. Zhang, Y. Tu, R. Xiang, Y.-L. Guo*, J. Zhang* Phosphine-Catalyzed Difunctionalization of β-Fluoroalkyl α,β-Enones: A Direct Approach to β-Amino α-Diazo Carbonyl Compounds. Angew. Chem. Int. Ed. 2018, 57, 15787–15791.
H. Wang, J. Zhan, Y. Tu, J. Zhang* Phosphine-Catalyzed Enantioselective Dearomative [3+2]-Cycloaddition of 3-Nitroindoles and 2-Nitrobenzofurans. Angew. Chem. Int. Ed. 2019, 58, 5422–5426.
Z.-M. Zhang, B. Xu, L. Wu, L. Zhou, D. Ji, Y. Liu, Z. Li*, J. Zhang* Palladium/XuPhos-Catalyzed Enantioselective Carboiodination of Olefin-Tethered Aryl Iodides. J. Am. Chem. Soc. 2019, 141, 8110–8115.
P.-C. Zhang, J. Han, J. Zhang* Pd/PC-Phos-Catalyzed Enantioselective Intermolecular Denitrogenative Cyclization of Benzotriazoles with Allenes and N-Allenamides. Angew. Chem. Int. Ed. 2019, 58, 11444–11448. (VIP)
Z.-M. Zhang, B. Xu, L. Wu, Y. Wu, Y. Qian, L. Zhou, Y. Liu, J. Zhang* Enantioselective Dicarbofunctionalization of Unactivated Alkenes by Palladium-Catalyzed Tandem Heck/Suzuki Coupling Reaction. Angew. Chem. Int. Ed. 2019, 58, 14653–14659.
C. Zhu, H. Chu, G. Li, S. Ma*, J. Zhang* Pd-Catalyzed Enantioselective Heck Reaction of Aryl Triflates and Alkynes. J. Am. Chem. Soc. 2019, 141, 19246–19251.
Q. Dai, W. Li, Z. Li, J. Zhang* P-Chiral Phosphines Enabled by Palladium/Xiao-Phos-Catalyzed Asymmetric P–C Cross-Coupling of Secondary Phosphine Oxides and Aryl Bromides. J. Am. Chem. Soc. 2019, 141, 20556–20564.
H. Wang, H. Luo, Z.-M. Zhang, W.-F. Zheng, Y. Yin, H. Qian*, J. Zhang*, S. Ma* Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids. J. Am. Chem. Soc. 2020, 142, 9763–9771.
L. Wang, K. Zhang, Y. Wang, W. Li, M. Chen, J. Zhang* Enantioselective Synthesis of Isoxazolines Enabled by Palladium-Catalyzed Carboetherification of Alkenyl Oximes. Angew. Chem. Int. Ed.2020, 59, 4421–4427.
L. Zhou, S. Li, B. Xu, D. Ji, L. Wu, Y. Liu, Z.-M. Zhang*, J. Zhang* Enantioselective Difunctionalization of Alkenes by a Palladium-Catalyzed Heck/Sonogashira Sequence. Angew. Chem. Int. Ed. 2020, 59, 2769–2775.
Q. Dai, L. Liu, Y. Qian, W. Li, J. Zhang* Construction of P-Chiral Alkenylphosphine Oxides through Highly Chemo-, Regio-, and Enantioselective Hydrophosphinylation of Alkynes. Angew. Chem. Int. Ed.2020, 59, 20645–20650.
H. Chu, J. Cheng, J. Yang, Y.-L. Guo*, J. Zhang * Asymmetric Dearomatization of Indole via Palladium/PC-Phos-Catalyzed Dynamic Kinetic Transformation. Angew. Chem. Int. Ed. 2020, 59, 21991–21996. (Hot Paper)
T.-Y. Lin, Z. Pan, Y. S. Zhu, H.-H. Wu, Y. Liu, Z. Li*, J. Zhang* Design and Synthesis of TY-Phos and Application in Palladium-Catalyzed Enantioselective Fluoroarylation of gem-Difluoroalkenes. Angew. Chem. Int. Ed. 2020, 59, 22957−22962.
D. Qian, J. Zhang* Yne–Enones Enable Diversity-Oriented Catalytic Cascade Reactions: A Rapid Assembly of Complexity. Acc. Chem. Res.2020, 53, 2358–2371.
Z. Pan, W. Li, S. Zhu, F. Liu, H.-H. Wu, J. Zhang* Palladium/TY-Phos-Catalyzed Asymmetric Intermolecular α-Arylation of Aldehydes with Aryl Bromides. Angew. Chem. Int. Ed.2021, 60, 18542–18546. (Hot Paper)
P.-C. Zhang, Y.-L. Li, J. He, H.-H. Wu*, Z. Li*, J. Zhang* Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation. Nat. Commun.2021, 12, 4609.
Y.-L. Li, P.-C. Zhang, H.-H. Wu, J. Zhang* Palladium-Catalyzed Asymmetric Tandem Denitrogenative Heck/Tsuji–Trost of Benzotriazoles with 1,3-Dienes. J. Am. Chem. Soc. 2021, 143, 13010–13015.
G. Zhao, Y. Wu, H.-H. Wu, J. Yang*, J. Zhang* Pd/GF-Phos-Catalyzed Asymmetric Three-Component Coupling Reaction to Access Chiral Diarylmethyl Alkynes. J. Am. Chem. Soc. 2021, 143, 17983–17988.
Q. Dai, L. Liu*, J. Zhang* Palladium/Xiao-Phos-Catalyzed Kinetic Resolution of sec-Phosphine Oxides by P-Benzylation. Angew. Chem. Int. Ed. 2021, 60, 27247–27252.
B. Xu, D. Ji, L. Wu, L. Zhou, Y. Liu, Z.-M. Zhang*, J. Zhang* Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction. Chem2022, 8, 836–849.
