邓勇辉

无机化学

教授,博士生导师

  yhdeng@fudan.edu.cn

  上海市杨浦区淞沪路2005号 复旦大学江湾校区化学楼 A5013室

  021-31243292

  http://www.yhdenggroup.fudan.edu.cn/

研究兴趣

早期研究工作重心:设计新型两亲性嵌段共聚物作为模板剂和结构导向剂,创制具有大孔径的介孔二氧化硅材料(如Si-FDU-18)、介孔酚醛树脂高分子材料及介孔碳材料如C-FDU-18(相关成果:J. Am. Chem. Soc. 2007, 129, 1690-1697;Chem. Mater. 2007, 19, 3271-3277;J. Mater. Chem. 2008, 18, 91-97;Chem. Mater. 2008, 20, 7281-7286;Chem. Mater. 2009, 21, 3996-4005;Adv. Funct. Mater. 2010, 20, 3658-3665等),这些新型介孔材料的孔径可在10-45 nm 范围连续调控,并可以用于孔内高效负载高活性催化组分,用于非均相催化反应。

2011年起,相关研究工作拓展到大孔径有序介孔金属氧化物材料的设计合成及应用研究中。目前主要研究工作以高性能催化及气体传感应用需求为牵引,致力于新型非均相介孔纳米催化材料和介孔气体传感材料的定向设计、化学剪裁合成与应用研究。运用高分子合成化学手段、超分子组装和模板合成方法及策略,结合胶体与界面科学的基本理论,有效地调控分子-分子、胶体(团簇)-分子、胶体-胶体之间的相互作用,进而在分子、纳米和介观尺度上实现纳米结构材料的可控合成与组装,创造出具有多丰富组成、协同效应的功能介孔材料。通过各种先进手段深入研究材料催化与气体传感机理,阐述结构、组成与性能的关系,并由此发展基于这些新型介孔材料的相关纳米器件及装备。

承担项目情况:

  • 作为首席负责国家重点研发计划“硅基气体敏感薄膜兼容制造及产业化平台关键技术研究”(制造基础技术与关键部件专项),主持国家杰出青年基金、上海市科委基础重大项目以及企业合作课题等近10项课题。

主要研究方向包括:

(1) 气敏传感功能导向的介孔金属氧化物半导体纳米材料:剪裁设计、化学合成及性能研究

(2) 新颖非均相介孔催化剂材料:微纳米尺度水平可控构筑及其催化功能探索

(3) 基于介孔催化和介孔传感材料的环境监测、生物医学、食品安全等领域的微纳器件及气体传感器装备

学术任职

  • 2012.09 - 至今   Advanced Porous Materials期刊的副主编

  • 2017.01 - 至今   担任 Chinese Chemical Letters 副主编

  • 2014.9 - 至今   澳大利亚Australian Research Council(ARC)基金国际评审专家(Assessor)

  • 2018 - 至今     上海市化学化工学会理事

  • 2018 - 至今     上海市军民融合研究会理事

  • 2019 - 至今     Journal of Colloid and Interface Science期刊的编委

  • 2019 - 至今     中国气湿敏传感技术专业委员会副主任委员

获奖情况

  • 2021  国家杰出青年科学基金

  • 2021  中国分子筛青年奖

  • 2020  国家自然科学一等奖(排名第三)

  • 2020  国家重点研发计划首席科学家

  • 2020  英国皇家化学会会士

  • 2019  上海市优秀青年学术带头人

  • 2014-2020  连续7年爱思维尔中国高被引用学者(材料科学)

  • 2017  教育部自然科学一等奖(排名第二)

  • 2015  教育部“青年长江学者”

  • 2014  国家优秀青年基金

  • 2014  教育部自然科学二等奖(排名第一)

  • 2014  上海市青年科技英才(基础类,全市共10人)

  • 2013  上海市曙光学者

  • 2012  第二十五届上海市优秀发明选拔赛优秀发明银奖

  • 2012  陶氏化学科研创新奖

  • 2012  教育部“新世纪优秀人才计划”

  • 2011  上海市科委“青年科技启明星跟踪计划”

  • 2009  国家留学基金委全额资助访问学者计划

  • 2008  明治乳业生命科学奖

  • 2008  上海市科委“青年科技启明星计划”

学习工作经 历

  • 2011年09月至今                 复旦旦大学化学系,教授

  • 2009年12月至2010年12月  加州大学伯克利分校,访问学者

  • 2007年09月至2011年08月  复旦大学化学系,副教授

  • 2005年10月至2007年09月  复旦大学,博士后

  • 2005年07月至2005年09月  Ciba Specialty Chemicals Corp(shanghai), 研发化学师

  • 2000年09月至2005年07月  复旦大学,高分子化学与物理专业,博士学位

  • 1996年09月至2000年07月  南昌大学,无机化学专业,学士学位

授课情况

  • 无皂乳液聚合法制备单分散高分子胶体微球

  • 二氧化钛光催化:合成与应用

代表性论文或专著

  • Xuanyu Yang, Yatong Shi, Kefeng Xie, Shaoming Fang, Yong-Hui Zhang*, Yonghui Deng*Cocrystallization Enabled Spatial Self-Confinement Gives Crystalline Porous Metal Oxide Nanosheets for Gas Sensing Angew. Chem. Int. Ed. 2022,134 (37), e202207816

  • Jing Wang#, Yuan Ren#, Hui Liu, Ziliang Li, Xinya Liu, Yonghui Deng*, Xiaosheng Fang* Ultrathin 2D NbWO6 Perovskite Semiconductor based Gas Sensors with Ultrahigh Selectivity under Low Working Temperature, Adv. Mater. 2021, 2104958

  • Yuan Ren#, Yidong Zou#, Yang Liu, Xinran Zhou, Junhao Ma, Dongyuan Zhao, Guangfeng Wei, Yuejie Ai, Shibo Xi, Yonghui Deng*, Synthesis of orthogonally assembled 3D cross-stacked metal oxide semiconducting nanowires., Nat Mater., 2020, 19 (2), 203–211.

  • Qin Yue, Jianguo Sun, Yijin Kang, Yonghui Deng*, Advances in the Interfacial Assembly of Mesoporous Silica on Magnetite Particles., Angew. Chem. Int. Ed. 2020, 59,15804 –15817

  • Liangliang Liu, Xuanyu Yang, Yujie Xie, Huan Liu, Xinran Zhou, Xingyu Xiao, Yuan Ren, Zhen Ma, Xiaowei Cheng, Yonghui Deng*, Dongyuan Zhao, A universal lab-on-salt-particle approach to 2D single-layer ordered mesoporous materials., Adv. Mater., 2020, 32 (10), 1906653.

  • Yidong Zou, Xinran Zhou, Junhao Ma, Xuanyu Yang, Yonghui Deng*, Recent advances in amphiphilic block copolymer templated mesoporous metal-based materials: assembly engineering and applications, Chem. Soc. Rev. 2020, 49, 1173–1208.

  • Yidong Zou, Xinran Zhou, Yongheng Zhu, Xiaowei Cheng, Dongyuan Zhao, Yonghui Deng*, sp2-Hybridized Carbon-Containing Block Copolymer Templated Synthesis of Mesoporous Semiconducting Metal Oxides with Excellent Gas Sensing Property, Acc. Chem. Res. 2019, 52 (3), 714–725.

  • Yu Zhang, Qin Yue, Lei Yu, Xuanyu Yang, Xiu-Feng Hou, Dongyuan Zhao, Xiaowei Cheng, Yonghui Deng*, Amphiphilic Block Copolymers Directed Interface Coassembly to Construct Multifunctional Microspheres with Magnetic Core and Monolayer Mesoporous Aluminosilicate Shell, Adv. Mater. 2018, 1800345

  • Qin Yue, Jialuo Li, Yu Zhang, Xiaowei Cheng, Xiao Chen, Panpan Pan, Jiacan Su*, Ahmed A. Elzatahry, Abdulaziz Alghamdi, Yonghui Deng*, Dongyuan Zhao, Plasmolysis-Inspired Nanoengineering of Functional Yolk-Shell Microspheres with Magnetic core and Mesoporous Silica Shell, J. Am. Chem. Soc., 2017, 139, 15486–15493.

  • Yongheng Zhu, Yong Zhao, Junhao Ma, Xiaowei Cheng, Jing Xie, Pengcheng Xu, Haiquan Liu, Hongping Liu, Haijiao Zhang, Minghong Wu, Ahmed A. Elzatahry, Abdulaziz Alghamdi, Yonghui Deng*, Dongyuan Zhao, Mesoporous Tungsten Oxides with Crystalline Framework for Highly Sensitive and Selective Detection of Foodborne Pathogens, J. Am. Chem. Soc., 2017, 139, 10365–10373

  • Qin Yue, Yu Zhang, Yongjian Jiang, Jialuo Li, Hongwei Zhang, Chengzhong Yu, Ahmed A. Elzatahry, Abdulaziz Alghamdi, Yonghui Deng*, Dongyuan Zhao, Nanoengineering of Core−Shell Magnetic Mesoporous Microspheres with Tunable Surface Roughness, J. Am. Chem. Soc., 2017, 139, 4954−4961.

  • Jing Wei, Zhenkun Sun, Wei Luo, Yuhui Li, Ahmed A. Elzatahry, Abdullah M. Al-Enizi, Yonghui Deng*, Dongyuan Zhao, New Insight into the Synthesis of Large-Pore Ordered Mesoporous Materials, J. Am. Chem. Soc., 2017, 139, 1706−1713.

  • Wei Luo, Tao Zhao, Yuhui Li, Jing Wei, Pengcheng Xu, Xinxin Li, Youwei Wang, Wenqing Zhang, Ahmed A. Elzatahry, Abdulaziz Alghamdi, Yonghui Deng*, Lianjun Wang, Wan Jiang, Yong Liu, Biao Kong, Dongyuan Zhao*, A Micelle Fusion-Aggregation Assembly Approach to Mesoporous Carbon Materials with Rich Active Sites for Ultra-Sensitive Ammonia Sensing, J. Am. Chem. Soc., 2016, 138, 12586−12595.

  • Zhenkun Sun, Xinran Zhou, Wei Luo, Qin Yue, Yu Zhang, Xiaowei Cheng, Wei Li, Biao Kong, Yonghui Deng*, Dongyuan Zhao, Interfacial engineering of magnetic particles with porous shells: Towards magnetic core –Porous shell microparticles, Nano Today, 2016, 11, 464-482.

  • Qin Yue, Jialuo Li, Wei Luo, Yu Zhang, Ahmed A. Elzatahry, Xiqing Wang, Chun Wang, Wei Li, Xiaowei Cheng, Abdulaziz Alghamdi, Aboubakr M. Abdullah, Yonghui Deng*, Dongyuan Zhao, An Interface Co-assembly in Bi-liquid Phase: Towards Core-Shell Magnetic Mesoporous Silica Microspheres with Tunable Pore Size, J. Am. Chem. Soc., 2015, 137, 13282-13289

  • Yuhui Li, Wei Luo, Nan Qin, Junping Dong, Jing Wei, Wei Li, Shanshan Feng, Junchen Chen, Jiaqiang Xu, Ahmed A. Elzatahry, Mahir H. Es-Saheb, Yonghui Deng*, Dongyuan Zhao, Highly Ordered Mesoporous Tungsten Oxides with a Large Pore Size and Crystalline Framework for H2S Sensing, Angew. Chem. -Int. Ed., 2014, 53(34), 9035-9040.

  • Minghong Wang, Zhenkun Sun, Qin Yue, Jie Yang, Xiqing Wang, Yonghui Deng*, Chengzhong Yu, Dongyuan Zhao, An Interface-Directed Co-assembly Approach to Synthesize Uniform Large-Pore Mesoporous Silica Spheres, J. Am. Chem. Soc., 2014, 136, 1884−1892.

  • Jing Wei, Yuyun Liu, Jia Chen, Yuhui Li, Qin Yue, Gaoxiang Pan, Yanlei Yu* , Yonghui Deng*, Dongyuan Zhao, Azobenzene-Derived Surfactants as Phototriggered Recycable Templates for the Synthesis of Azobenzene-Derived Surfactants as ordered Mesoporous Silica Nanospheres, Adv. Mater., 2014, 26(11), 1782-1787.

  • Yonghui Deng, Jing Wei, Zhenkun Sun Dongyuan Zhao*, Large-pore ordered mesoporous materials templated from non-Pluronic amphiphilic block copolymers, Chem. Soc. Rev., 2013, 42 (9), 4054 - 4070.

  • Chun Wang, Jing Wei, Qin Yue, Wei Luo, Yuhui Li, Minghong Wang, Yonghui Deng,* Dongyuan Zhao, A Shear Stress Regulated Assembly Route to Silica Nanotubes and Their Closely Packed Hollow Mesostructures, Angew. Chem. Int. Ed., 2013, 52(44), 11603-11606.

  • Wei Li, Qin Yue, Yonghui Deng*, Dongyuan Zhao, Ordered Mesoporous Materials Based on Interfacial Assembly and Engineering, Adv. Mater., 2013, 25(37), 5129-5152.

  • Wei Luo, Yuhui Li, Junping Dong, Jing Wei, Jiaqiang Xu, Yonghui Deng*, Dongyuan Zhao*, A Resol-Assisted Co-Assembly Approach to Crystalline Mesoporous Niobia Spheres for Electrochemical Biosensing, Angew. Chem. Int. Ed., 2013, 52(40), 10505-10510.

  • Zhenkun Sun, Bo Sun, Minghua Qiao, Jing Wei, Qin Yue, Chun Wang, Yonghui Deng*, Serge Kaliaguine, Dongyuan Zhao*, A General Chelate-Assisted Co-Assembly to Metallic Nanoparticles-Incorporated Ordered Mesoporous Carbon Catalysts for Fischer-Tropsch Synthesis, J. Am. Chem. Soc., 2012, 134 (42), 17653-17660.

  • Qin Yue, Minghong Wang, Jing Wei, Yonghui Deng*, Tianyi Liu, Renchao Che, Bo Tu, Dongyuan Zhao*, A Template Carbonization Strategy to Synthesize Ordered Mesoporous Silica Microspheres with Trapped Sulfonated Carbon Nanoparticles for Efficient Catalysis, Angew. Chem. -Int. Ed., 2012, 51(41), 10368-10372.

  • Jing Wei, Qin Yue, Zhenkun Sun, Yonghui Deng*, Dongyuan Zhao*, Synthesis of Dual-Mesoporous Silica Using Non-Ionic Diblock Copolymer and Cationic Surfactant as Co-Templates, Angew. Chem. -Int. Ed., 2012, 51(25), 6149-6153

  • Jing Wei, Hai Wang, Yonghui Deng*, Zhenkun Sun, Lin Shi, Bo Tu, Mohammad Luqman, Dongyuan Zhao*, Solvent Evaporation Induced Aggregating Assembly Approach to Three-Dimensional Ordered Mesoporous Silica with Ultralarge Accessible Mesopores, J. Am. Chem. Soc., 2011, 133 (50), 20369-20377.

  • Wei Li, Yonghui Deng*, Zhangxiong Wu, Xufang Qian, Jianping Yang, Yao Wang, Dong Gu, Fan Zhang, Bo Tu, Dongyuan Zhao*, Hydrothermal Etching Assisted Crystallization: A Facile Route to Functional Yolk-Shell Titanate Microspheres with Ultrathin Nanosheets-Assembled Double Shells, J. Am. Chem. Soc., 2011,133 (40), 15830-15836.

  • Junyong Zhang, Yonghui Deng*, Dong Gu, Shutao Wang, Lan She, Renchao Che, Zhong-Sheng Wang, Bo Tu, Songhai Xie, Dongyuan Zhao*, Ligand-Assisted Assembly Approach to Synthesize Large-Pore Ordered Mesoporous Titania with Thermally Stable and Crystalline Framework, Adv. Energy Mater., 2011, 1(2), 241-248.

  • Yonghui Deng, Yue Cai, Zhenkun Sun, Jia Liu, Chong Liu, Jing Wei, Wei Li, Chang Liu, Yao Wang Dongyuan Zhao*, Multifunctional Mesoporous Composite Microspheres with Well-Designed Nanostructure: A Highly Integrated Catalyst System, J. Am. Chem. Soc., 2010, 132 (24), 8466-8473.

  • Jia Liu, Zhenkun Sun, Yonghui Deng*, Ying Zou, Chunyuan Li, Xiaohui Guo, Liqin Xiong, Yuan Gao, Fuyou Li, Dongyuan Zhao*, Highly Water-Dispersible Biocompatible Magnetite Particles with Low Cytotoxicity Stabilized by Citrate Groups, Angew. Chem. -Int. Ed., 2009, 48(32), 5875-5879.

  • Yonghui Deng, Chunhui Deng, Dawei Qi, Chong Liu, Jia Liu, Xiangmin Zhang, Dongyuan Zhao*, Synthesis of Core/Shell Colloidal Magnetic Zeolite Microspheres for the Immobilization of Trypsin, Adv. Mater., 2009, 21(13), 1377 - 1382.

  • Yonghui Deng, Dawei Qi, Chunhui Deng*, Xiangmin Zhang, Dongyuan Zhao*, Superparamagnetic High-Magnetization Microspheres with an Fe3O4@SiO2 Core and Perpendicularly Aligned Mesoporous SiO2 Shell for Removal of Microcystins, J. Am. Chem. Soc., 2008, 130, 28-29.

  • Yonghui Deng, Ting Yu, Ying Wan, Yifeng Shi, Yan Meng, Dong Gu, Lijuan Zhang, Yan Huang, Chong Liu, Xiaojing Wu, Dongyuan Zhao*, Ordered Mesoporous Silicas and Carbons with Large Accessible Pores Templated from Amphiphilic Diblock Copolymer Poly(ethylene oxide)- b -polystyrene, J. Am. Chem. Soc., 2007, 129 (6), 1690 - 1697.

  • Yonghui Deng, Wuli Yang, Changchun Wang, Shoukuan Fu, A novel approach for preparation of thermoresponsive polymer magnetic microspheres with core-shell structure, Adv. Mater., 2003, 15(20), 1729-1732.