EN

贺鹤勇物理化学,教授,博士生导师

电子邮箱:heyonghe@fudan.edu.cn
办公地点:上海市杨浦区淞沪路2005号 复旦大学江湾校区化学楼 A2007室
电话:86-21-31243916
课题组主页:http://heyonghe-chem.fudan.edu.cn/

  • 研究兴趣

  • 学术任职

  • 获奖情况

  • 学习工作经历

  • 授课情况

  • 代表性论文或专著

  • 低碳烷烃的功能化(甲烷二氧化碳重整等)

  • 酸催化

  • 多相催化加氢和手性加氢

  • 苯羟基化制苯酚催化剂研究

  • 模型催化剂和催化反应机理研究

  • 《催化学报》编委

  • 《波谱学报》编委

  • 中国化学会催化专业委员会委员

  • 中国物理学会波谱学专业委员会委员

  • 上海市化学化工学会副理事长


  • 1980.10-1984.6   复旦大学化学系本科,获得理学学士学位

  • 1984.6-1989.6     复旦大学化学系助教

  • 1989.6-1990.6     英国伦敦帝国理工学院化学系访问学者

  • 1990.7-1993.9     英国剑桥大学化学系研究生,获得理学博士学位

  • 1993.10-1997.7   英国剑桥大学化学系固体核磁共振实验室Manager

  • 1997.8-2000.3     英国利物浦大学化学系Leverhulme催化中心Principal Scientist

  • 2000.4起               复旦大学化学系教授

    固体核磁共振及其在结构表征和催化反应机理研究中的应用

  1. X. Li, Y.H. Ren, Z.W. Weng, B. Yue, H.Y. He. Stabilization of high-valent Cu3+ in a Keggin-type polyoxometalate. Chem. Commun. 56, 2324-2327 (2020).

  2. Y.N. Wu, D.F. Huang, Y.Y. Fu, L. Zhang, S.X. Liu, G.F. Tang, Y.H. Ren, L. Ye, .X.Y. Chen, B. Yue, H.Y. He.Investigation on surface acidic properties of the facet-dependent sulfated Cu2O solids by 31P MAS NMR. Chem.-A Eur J. 25, 14771-14774 (2019).

  3. Y.N. Wu, Y.Y. Fu, L. Zhang, Y.H. Ren, X.Y. Chen, B. Yue* H.Y. He. The study of oxygen vacancies on different facets of anatase TiO2. Chin. J. Chem. 37, 922-928 (2019).

  4. X.Y. Gao, X.Y. Chen, Z.H. Li, H.Y, He. Direct synthesis of in-situ chirally modified palladium nanocrystals without capping agents and their application in heterogeneous enantioselective hydrogenations. ACS Catal. 9, 6100-6110 (2019).

  5. Y.Y. Fu, L. Zhang, B. Yue, X.Y. Chen, H.Y. He. Simultaneous characterization of solid acidity and basicity of metal oxide catalysts via solid state NMR technique. J. Phys. Chem. C 122, 24094-24102 (2018).

  6. N. Su, X.Y. Gao, X.Y. Chen, B. Yue, H.Y He. The enantioselective hydrogenation of acetophenone over Pd concave tetrahedron nanocrystals affected by the residual adsorbed capping agent polyvinylpyrrolidone (PVP). J. Catal. 367, 244-251 (2018).

  7. N. Su, X.Y. Chen, B. Yue, H.Y. He. Formation of palladium concave nanocrystals via auto-catalytic tip overgrowth by interplay of reduction kinetics, concentration gradient and surface diffusion. Nanoscale 8, 8673-8680 (2016).

  8. Y.C. Hu, B. Guo, Y.Y. Fu, Y.H. Ren, G.F. Tang, X.Y. Chen, B. Yue, H.Y. He. Facet-dependent acidic and catalytic properties of sulfated   titania   solid superacids. Chem. Commun. 51, 14219-14222 (2015).

  9. L.P. Qian, W.J. Cai, L. Zhang, L. Ye, J. Li, M. Tang, B. Yue, H.Y. He. The promotion effect of hydrogen spillover on CH4 reforming with CO2 over Rh/MCF catalysts. Appl. Catal. B: Environ. 164, 168-175 (2015).

  10. Y. Wang, N. Su, L. Ye, Y.H. Ren, X.Y. Chen, Y.J. Du, Z.H. Li, B Yue, S.C. Tsang, Q. Chen, H.Y He. Tuning enantioselectivity in asymmetric   hydrogenation of acetophenone and its derivatives via confinement effect over free-standing mesoporous Pd network catalysts. J. Catal. 313,   113-126 (2014).

  11. L.Y. Hu, B. Yue, H.Y. He. Direct hydroxylation of benzene to phenol on Cu-V bimetal modified HMS catalysts. Catal. Commun. 43, 179-183 (2014).

  12. L. Zhang, Y.H. Ren, B. Yue, H.Y. He. Recent development in in situ NMR study on catalytic reaction mechanisms of light alkane functionalization. Chem. Commun. 48, 2370-2384 (2012).

  13. Y.H. Ren, C.B. Du, S.J. Feng, C.L. Wang, Z.P. Kong, B. Yue, H.Y. He. Three POM-based coordination polymers: hydrothermal synthesis, characterization, and catalytic activity in epoxidation of styrene. CrysEngComm. 13, 7143-7148 (2011).

  14. L. Ye, Y. Wang, X.Y. Chen, B. Yue, S.C. Tsang, H.Y. He. Three-dimentionally ordered mesoporous Pd networks templated by silica super crystal and their application in formic acid electrooxidation. Chem. Commun. 47, 7389-7391 (2011).

  15. L.P. Qian, Y. Ren, H. Yu, Y. Wang, B. Yue, H.Y. He. Controlled atmosphere 13C and 1H MAS NMR study of reforming route of methane with carbon dioxide over Rh/SBA-15. Appl. Catal. A: Gen. 401, 114-118 (2011).

  16. C.L. Wang, Y.H. Ren, C.B. Du, B. Yue, Z.P. Kong, L.H. Weng, H.Y. He. Honeycomb nanoscale-porous material constructed from copper complexes and mixed-addenda Lindqvist-type polyoxoanions. CrystEngComm 12, 3522-3525 (2010).

  17. X.Y. Chen, Z.Y. Lou, M.H. Qiao, K.N. Fan, S.C. Tsang, H.Y. He. Hexagonally packed Pd nanoarray catalyst for liquid phase enantioselective hydrogenation of acetophenone to R-(+)-1-phenylethanol in the presence of S-proline. J. Phys. Chem. C. 112, 1316-1320 (2008).

  18. X.Y. Chen, M.H. Qiao, S.H. Xie, K.N. Fan, W.Z. Zhou, H.Y. He. Icositetrahedra of zeolite analcime with a polycrystalline core: a reversed crystal growth route. J. Am. Chem. Soc. 129, 13305-13312 (2007).

  19. Y.C. Li, S.R. Yan, L.P. Qian, W.M. Yang, Z.K. Xie, Q.L. Chen, B. Yue, H.Y. He. Effect of tin on Nb2O5/α-Al2O3 catalyst for ethylene oxide hydration. J. Catal. 241, 173-179 (2006).

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