杨俊锋
  • 研究兴趣

  • 学术任职

  • 获奖情况

  • 学习工作经历

  • 授课情况

  • 代表性论文或专著

  • 过渡金属催化

  • 廉价金属化学

  • 不对称合成

  • 绿色化学



  • 2004.9-2008.6           郑州大学化学系本科,获得理学学士学位

  • 2009.8-2014.5           新加坡南洋理工大学化学与生物化学系研究生, 获得理学博士学位

  • 2014.5-2018.11         新加坡南洋理工大学Research Fellow

  • 2018.12-起                复旦大学化学系青年研究员

    有机合成及反应机理

  1. Ma, C.; Wang, X.; Zhang, J.;* Yang, J.* Ligand-controlled regiodivergent and enantioselective hydrophosphorylation of styrenes by palladium. Chem 2024. under revision

  2. Yuan, Y.; Han, Y.; Zhang, Z.-K.; Sun, S.; Wu, k.; Li, J.; Yang, J.;* Zhang, J.* Enantioselective Arylation of Sulfenamides to Access Sulfilimines Enabled by Palladium Catalysis. Angew. Chem. Int. Ed.2024. 63, e202409541.

  3. Yi, X.; Yuan, Y.; Li, J.; Yang, J.;* Zhang, J.* Catalytic Asymmetric Synthesis of Sulfinamides via Cu-Catalyzed Asymmetric Addition of Aryl Boroxines to Sulfinylamines. J. Am. Chem. Soc.2024. 146, 17580–17586.

  4. Cao, K.; Han, J.; Ye, W.; Hu, D.; Ye, Z.; Yang, J.;* Zhang, J.;* Chen, F. * Palladium-Catalyzed Enantioselective Intramolecular Aminosilylation of Alkenes. Adv. Sci.2024, DOI: 10.1002/advs.202403470.

  5. Cao, K.; Qi, S.; Li, J.; Ye, W.; Yang, J.;* Zhang, J.; * Chen, F. * Palladium-catalyzed tandem aza-Heck reaction of alkene-tethered oxime esters with cyclopropanols. Green Synth. Catal. 2024, 10.1016/j.gresc.2024.04.002.

  6. Zhang, G.; Yang, B.; Yang, J.;* Zhang, J.* Pd-Catalyzed Asymmetric Larock Indole Synthesis to Access Axially Chiral N-arylindoles. J. Am. Chem. Soc. 2024, 146, 5493–5501.

  7. Qi, S.; Hua, Y.; Pan, L.; Yang, J.;* Zhang, J.* Nickel-Catalyzed Regio- and Stereoselective Defluorinative Arylation of gem-Difluorinated Cyclopropanes. Chin. J. Chem. 2024, 42, 823-828.

  8. Han, Y.; Yuan, Y.; Qi, S.; Zhang, Z.-K.; Kong, X.; Yang, J.;* Zhang, J. * Copper-Catalyzed Sulfur Alkylation of Sulfenamides with N-Sulfonylhydrazones. Org. Lett.2024, 26, 3906-3910.

  9. Qi, S.; Ye W.; Hua, Y.; Pan, L.; Yang, J.;* Zhang, J.* Ligand-Enabled Pd-Catalyzed Enantioselective Synthesis of Quaternary Amino Acids and Glycolic Acids Derivatives. Nat. Synth.2024, 3, 357-367

  10. Cao, K.; Han, J.; Shen, H.; Yang, J.; * Zhang, J. *Chen, F. * Pd-Catalyzed Asymmetric Narasaka-Heck Cycliza-tion/Sonogashira Reaction of Alkene-Tethered Oxime Esters and Terminal Alkynes. ACS Catal. 2024, 14, 5305-5313.

  11. Gao, S.; Wang, C.; Yang, J.;* Zhang, J. * Cobalt-Catalyzed Enantioselective Intramolecular Reductive Cyclization via Electrochemistry. Nat. Commun.2023, 14, 1301.

  12. Ma, C.; Sun, Y.; Yang, J.; * Guo, H.; * Zhang, J. * Catalytic Asymmetric Synthesis of Tröger’s Base Analogues with Nitrogen Stereocenter. ACS Cent. Sci.2023, 9, 64-71.

  13. Yuan, Y.; Yang, J.;* Zhang, J.* Cu-catalyzed enantioselective decarboxylative cyanation via the synergistic merger of photocatalysis and electrochemistry. Chem. Sci.2023, 14, 705-710.

  14. 14.Yang, B.; Cao, K.; Zhao, G.; Yang, J.; * Zhang, J. * Pd/Ming-Phos-Catalyzed Asymmetric Three-Component Arylsilylation of N-Sulfonylhydrazones: Enantioselective Synthesis of gem-Diarylmethine Silanes. J. Am. Chem. Soc.2022, 144, 15468-15474.

  15. Ma, C.; Sun, Y.; Liu, S.; Li, Z.; Yang, J; * Guo, H; * Zhang, J. * Enantioselective Construction of Axially Chiral Cyclohexylidenes Scaffolds via Pd-Catalyzed Asymmetric Coupling Reaction. Chem Catal.2022, 2, 3196 -3206.

  16. Li, S.; Chen, Q.; Yang, J.; * Zhang, J. * Palladium-Catalyzed Enantioselective γ-Arylation of β,γ-Unsaturated Butenolides. Angew. Chem. Int. Ed. 2022, 61, e202202046.

  17. Bao, H.; Shi, Y.; Zhang, J.; * Yang, J.; * Wu, J. * Stereoselective synthesis of trisubstituted epoxides via cobalt catalysis. Org. Chem. Front. 2022, 9, 4932 -4936

  18. Yang, B.; Yang, J.; * Zhang, J. * Synthesis of Axially Chiral Anilides Enabled by a Palladium/ Ming-Phos-Catalyzed Desymmetric Sonogashira Reaction. Chin. J. Chem.2022, 40, 317-322.

  19. Xie, X.; Li, S.; Chen, Q.; Guo, H.; Yang, J.; * Zhang, J. * Synthesis and application of novel P-chiral monophosphorus ligands. Org. Chem. Front.2022, 9, 1589-1592.

  20. Zhang, J.; Ni, H.; Wu, Q.; Yang, J.; * Zhang, J. * Development of P, S and Si-Stereogenic Compounds Synthesis via Palladium Catalysis. Chinese J. Org. Chem. 2022, 42, 3118-3128.

  21. Zhang, Y.; Pan, Z.; Guo, H.; Yang, J.; * Zhang, J. * 10 Gram-scale synthesis of TY-Phos ligand and its application in carbene insertion of Si-H bonds. Tetrahedron Lett.2022, 107, 154120.

  22. Gao, S.; Liu, C.; Yang, J.; * Zhang, J. * Cobalt-Catalyzed Electrochemical Reductive Coupling of Alkynes and Alkenes. Chinese J. Org. Chem.2022, 1559-1565.

  23. 23.Zhao, G.; Wu, Y.; Wu, H.-H.; Yang, J.; * Zhang, J. * Pd/GF-Phos-Catalyzed Asymmetric Three-Component Coupling Reaction to Access Chiral Diarylmethyl Alkynes. J. Am. Chem. Soc. 2021, 143, 17983-17988.

  24. Li, S.; Chen, Q.; Xie, X.; Yang, J.; * Zhang, J. * Pd-Catalyzed Enantioselective Dearomative Allylic Annulation to Access PPAPs Analogues. Org. Lett. 2021, 23, 7824-7828.

  25. Chen, Q.; Li, S.; Xie, X.; Guo, H.; Yang, J.; * Zhang, J. * Pd-Catalyzed Enantioselective Dicarbofunctionalization of Alkene to Access Disubstituted Dihydroisoquinolinone. Org. Lett.2021, 23, 4099-4103.

  26. Yang, J.; * Mori, Y.; Yamanaka, M.; * Yoshikai, N. * Cobalt-Catalyzed Intramolecular Hydroacylation Involving Cyclopropane Cleavage. Chem. Eur. J.2020, 26, 8302-8307.

  27. Qi, S.; Gao, S.; Xie, X.; Yang, J.; * Zhang, J. * Palladium-Catalyzed Fluoroarylation of gem-Difluoroenynes to Access Trisubstituted Trifluoromethyl Allenes. Org. Lett.2020, 22, 5229-5234.

  28. Chu, H.; Cheng, J.; Yang, J.; Guo, Y. L.; Zhang, J., * Asymmetric Dearomatization of Indole by Palladium/PC‐Phos‐Catalyzed Dynamic Kinetic Transformation. Angew. Chem. Int. Ed. 2020, 59, 4421-4427.

  29. Yang, J.; * Sun, Q.; Yoshikai, N. * Cobalt-Catalyzed Regio- and Diastereoselective Formal [3 + 2] Cycloaddition between Cyclopropanols and Allenes. ACS Catalysis2019, 9, 1973-1978.

  30. Yang, J. *; Sekiguchi, Y.; Yoshikai, N. * Cobalt-Catalyzed Enantioselective and Chemodivergent Addition of Cyclopropanols to Oxabicyclic Alkenes. ACS Catalysis 2019, 9, 5638-5644.

  31. Yang, J.; Shen, Y.; Lim, Y. J.; Yoshikai, N. *, Divergent ring-opening coupling between cyclopropanols and alkynes under cobalt catalysis. Chemical Science2018, 9, 6928-6934.

  32. Yang, J.; Rérat, A.; Lim, Y. J.; Gosmini, C.; Yoshikai, N. *, Cobalt-Catalyzed Enantio- and Diastereoselective Intramolecular Hydroacylation of Trisubstituted Alkenes. Angew. Chem. Int. Ed.2017, 56, 2449-2453.

  33. Yang, J.; Yoshikai, N. *, Cobalt-Catalyzed Annulation of Salicylaldehydes and Alkynes to Form Chromones and 4-Chromanones. Angew. Chem. Int. Ed. 2016, 55, 2870-2874.

  34. Yang, J.; Seto, Y. W.; Yoshikai, N. *, Cobalt-catalyzed intermolecular hydroacylation of olefins through chelation-assisted imidoyl C-H activation. ACS Catalysis2015, 5, 3054-3057.

  35. Yang, J.; Zhou, J. *, A general method for asymmetric arylation and vinylation of silyl ketene acetals. Organic Chemistry Frontiers2014, 1, 365-367.

  36. Yang, J.; Yoshikai, N. *, Cobalt-catalyzed enantioselective intramolecular hydroacylation of ketones and olefins. J. Am. Chem. Soc.2014, 136, 16748-16751.

  37. Yang, J.; Liu, S.; Zheng, J. F.; Zhou, J. *, Room-temperature Suzuki-Miyaura coupling of heteroaryl chlorides and tosylates. Eur. J. Org. Chem.2012, 6248-6259.