Inorganic Chemistry
Professor
xfhou@fudan.edu.cn
Room A8014, Chemistry Building, Department of Chemistry, Fudan University 2005 Songhu Road, Yangpu District, Shanghai 200438, China
86-21-31244878
Functionalized organometallic complexes and catalysis mechanism
Organometallic complexes supported materials and catalytic reaction
1981.9-1985.6 Bachelor Shaanxi Normal University
1985.9-1988.6 Master Central China Normal University
1988.9-1995.8 Lecturer YiLi Normal College
1995.9-1999.1 Ph D Fudan University
1999.1-2000.12 Post Doctor Postdoctoral program of Shanghai Petrochemical
Company Limited - Fudan University
2006.9-2007.8 Visiting Researcher Konstanz University
2001.1- Professor Fudan University
General Chemistry; Introduction of Organometallic Chemistry
X.-J. Chen, B. Zhan, X.-F. Hou*, Effect of silicon sources on the synthesis of nanosized beta zeolite aggregates as catalysts for conversion of lactic acid to lactide, ACS Appl. Nano Mater., 2025, 8, 11228−11239
X. Hong, Y.-W. Zhang, B. Zhan, X.-J. Chen, D.-J. Hu, Z.-M. Li*, X.-F. Hou*, Dual-role catalysis of iridium in photo-irradiation synthesis of 9-fluorenones through intramolecular cyclization via hydrogen evolution, Catal. Sci. Technol.,2024, 14, 638–645
B. Zhan, X. Hong, C. Li, X.-J. Chen, S. Liu*, X.-F. Hou*,Biomass-based N, S co-doped hierarchical porous carbon for selective adsorption of Au(III): Facile gold recovery from secondary wastes, ACS Sustainable Resour. Manage.,2024, 1, 1160−1169.
H.-Z. Cui, Z.-M. Zhang, H. Zhang, A. Reheman, X. Hong, B. Zhan, J. Zhang, X.-F. Hou*, Mesocellular silica foams supported size-controlled Pd nanoparticles for racemic and asymmetric iodomethyl dihydrobenzofuran synthesis, Microporous Mesoporous Mater., 2021, 322, 111157.
S. Huang, X. Hong, H.-Z. Cui, B. Zhan, Z.-M. Li* and X.-F. Hou*, Bimetallic bis-NHC-Ir(III) complex bearing 2arylbenzo[d]oxazolyl ligand: Synthesis, catalysis, and bimetallic effects, Organometallics, 2020, 39, 3514-3523.
X. Hong, Q. Zhou, S. Huang, H.-Z. Cui, Z.-M. Li * and X.-F. Hou *,Transition metal catalysed C7 and ortho-selective halogenation of 2-arylbenzo[d]oxazoles, Org. Chem. Front., 2019, 6, 2226-2233.
Q. Zhou, X. Hong, H.-Z. Cui, S. Huang, Y. Yi, X.-F. Hou*, The construction of C−N, C−O, and C(sp2)−C(sp3) bonds from fluorine-substituted 2aryl benzazoles for direct synthesis of N, O, Cfunctionalized 2-aryl benzazole derivatives. J. Org. Chem., 2018, 83, 6363-6372.
J.-Fan Zhang, R. Zhong, Q. Zhou, X. Hong, S. Huang, H.-Z. Cui and X.-F. Hou*, Recyclable silica-supported iridium catalysts for selective reductive transformation of quinolines with formic acid in water, ChemCatChem, 2017, 9, 2496 -2505.
Q. Zhou, J.-F. Zhang, H. Cao, R. Zhong and X.-F. Hou*,Synthesis of o-alkenylated 2-arylbenzoxazoles via Rh-catalyzed oxidative olefination of 2-arylbenzoxazoles: scope investigation, structural features, and mechanism studies, J. Org. Chem., 2016, 81, 12169-12180.
H. Cao, X.-H. Zhu, D. Wang, Z. Sun, Y. Deng, X.-F. Hou* and D. Zhao, Selectivity enhancement in dynamic kinetic resolution of secondary alcohols through adjusting the micro-environment of metal complex confined in nanochannels: A promising strategy for tandem reactions, ACS Catal.,2015, 5, 27−33.
Q. Zhou, Y.-N. Wang, X.-Q. Guo, X.-H. Zhu, Z.-M. Li*, X.-F. Hou*, Imino-N-heterocyclic carbene palladium(II) complex-catalyzed direct arylation of electron-deficient fluoroarenes with “on and off” chelating effect assistance, Organometallics, 2015, 34, 1021–1028.
D. Wang, X.-Q. Guo, C.-X. Wang, Y.-N. Wang, R. Zhong, X.-H. Zhu, L.-H. Cai, Z.-W. Gao* and X.-F. Hou*, An efficient and recyclable catalyst for N-alkylation of amines and β-alkylation of secondary alcohols with primary alcohols: SBA-15 supported N-heterocyclic carbene iridium complex, Adv. Synth. Catal., 2013, 355, 1117-1125.
Y.-N. Wang, X.-Q. Guo, X.-H. Zhu, R. Zhong, L.-H. Cai and X.-F. Hou*, Pd(OAc)2 catalyzed direct arylation of electron-deficient arenes without ligands or with monoprotected amino acid assistance, Chem. Comm., 2012, 48 (84), 10437 – 10439.
R. Zhong, Y.-N. Wang, X.-Q. Guo, Z.-X. Chen and X.-F. Hou*, Preparation of mononuclear, homodinuclear, and heterotrinuclear complexes by salicylaldiminato-functionalized imidazolium salt: Approach to multifunctional catalysts, Chem. Eur. J., 2011, 17, 11041-11051.