张立新

无机化学

教授,博士生导师

lixinzh@fudan.edu.cn

上海市杨浦区淞沪路2005号 复旦大学江湾校区化学楼 A7007室

021-31249192

研究兴趣

  • 稀土金属有机化学、烯烃聚合催化剂的开发

获奖情况

  • 2022 陶氏化学科研创新奖

学习工作经历

  • 2018年12月 - 现在                 复旦大学化学系,教授

  • 2008年07月 - 2018年11月    复旦大学化学系,副研究员

  • 2003年08月 - 2008年07月    日本理化学研究所,侯金属有机研究室,博士后

  • 2002年03月 - 2003年06月    台北中央研究院化学所,博士后

  • 2000年11月 - 2002年02月    德国汉堡大学,无机和应用化学研究所, 博士后

  • 1997年09月 - 2000年09月    复旦大学化学系,理学博士

  • 1994年09月 - 1997年07月    安徽师范大学有机化学研究所,理学硕士

  • 1990年09月 - 1994年07月    武汉工程大学,工学学士学位

授课情况

  • 有机实验化学、有机合成实验化学、无机合成(研究生)、无机合成实验(研究生)

代表性论文或专著

  • Rare-earth metal ethylene and ethyne complexes.Wen Jiang, T. Rajeshkumar, Mengyue Guo, Yuejian Lin, Laurent Maron*, Lixin Zhang*. Chem. Sci., 2024, 15, 3495–3501.

  • A binuclear guanidinate yttrium carbyne complex: unique reactivity toward unsaturated C–N, C–O and C–S bonds† Wen Jiang, Feng Kong, Iker del Rosal, Meng Li, Kai Wang, Laurent Maron * and Lixin Zhang*Chem. Sci., 2023, 14, 9154–9160.

  • Living 3,4-(Co)Polymerization of Isoprene/Myrcene and One-Pot Synthesis of a Polyisoprene Blend Catalyzed by Binuclear Rare-Earth Metal Amidinate Complexes Xiaying Yu, Meng Li, Jianquan Hong, Xigeng Zhou,* and Lixin Zhang*, Chem. Eur. J. 2019, 25, 2569 – 2576.

  • Isoprene Regioblock Copolymerization: Switching the Regioselectivity by the in situ Ancillary Ligand Transmetalation of Active Yttrium Species. Xiaying Yu, Qing You, Xigeng Zhou,* and Lixin Zhang *. ACS Catalysis,2018, 8, 4465.

  • Reversing Conventional Reactivity of Mixed Oxo/Alkyl Rare-Earth Complexes: Non-Redox Oxygen Atom Transfer. Jianquan Hong, Haiwen Tian, Lixin Zhang*, Xigeng Zhou*, Iker del Rosal, Linhong Weng, Laurent Maron*. Angew. Chem., Int. Ed., 2018, 57, 1062.

  • Unprecedented Reaction Mode of Phosphorus in Phosphinidene Rare-Earth Complexes: A Joint Experimental−Theoretical Study. Haiwen Tian,Jianquan Hong,Kai Wang,Iker del Rosal,Laurent Maron*,Xigeng Zhou*,Lixin Zhang*.  J. Am. Chem. Soc.,2018, 140, 102.

  • Homoetallic Rare Earth Metal Phosphinidene Clusters: Synthesis and Reactivity. Kai Wang, Gen Luo, Jianquan Hong, Xigeng Zhou*, Yi Luo*, Linhong Weng, Lixin Zhang*. Angew. Chem., Int. Ed.,2014, 53, 1053.

  • Methylidene Rare-earth Metal Complexes-mediated Transformations of C=N, N=N and N-H Bonds: New Routes to Imido Rare-Earth Metal Clusters. Jianquan Hong, Lixin Zhang*, Kai Wang, Yin Zhang, Linhong Weng, and Xigeng Zhou*. Chem., Eur. J.,2013, 19, 7865.

  • Syntheses, Structures, and Reactivities of Homometallic Rare Earth Metal Multimethyl Methylidene and Oxo Complexes. Jianquan Hong, Lixin Zhang*, Xiaying Yu, Meng Li, Zhengxing Zhang, Pengzhi Zheng, Masayoshi Nishiura, Zhaomin Hou, Xigeng Zhou*. Chem., Eur. J. , 2011, 17, 2130.

  • Isoprene Polymerization by Amidinate-Ligated Yttrium Catalysts. Switch the Regio- and Stereoselectivity by AlMe3. Lixin Zhang, Masayoshi Nishiura, Masahiro Yuki, Yi Luo, and Zhaomin Hou*. Angew. Chem., Int. Ed., 2008, 47, 2642.

  • Cationic Rare Earth Metal Alkyls bearing a Bis-(phosphinophenyl)amido (PNP) Ancillary Ligand. An Excellent Catalyst System for Living cis-1,4-Polymerization and Copolymerization of Isoprene and Butadiene.Lixin Zhang, Toshiaki Suzuki, Yi Luo, Masayoshi Nishiura, and Zhaomin Hou*. Angew. Chem., Int. Ed., 2007, 46, 1909.

  • Unprecedented Isospecific 3,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Resulting from a Binuclear Precursor. Zhang Lixin, Luo Yi, Hou Zhaomin*. J. Am. Chem. Soc., 2005, 127(42), 14562.

  • 通过链转移反应制备异戊二烯、月桂烯的区域嵌段共聚物的方法。张立新,郁夏盈。中国发明专利申请号2014102379120。

  • 招生方向:金属有机化学、配位化学与高分子合成。