师资队伍
钱辉
有机化学
副教授，博士生导师
qian_hui@fudan.edu.cn
遗传学楼412室
86-21-65648893
研究兴趣
-不对称催化
-联烯的合成及其在合成中的应用
-药物化学
获奖情况
2014年 Young Scientist Award (HKUST)
2018年 入选上海市“科技创新行动计划”扬帆计划
2023年 入选上海市“科技创新行动计划”启明星计划
2023年 入选国家高层次人才特殊支持计划青年拔尖人才
2024年 Thieme Chemistry Journals Award
学习工作经历
2007.08 – 2011.06 扬州大学化学化工学院，获得工学学士学位
2011.08 – 2015.08 香港科技大学化学系，获得理学博士学位
2016.10起 复旦大学化学系青年研究员
代表性论文或专著
11.Chen, Z.1; Wang, H.1; Du, P.; Zhao, J.; Zhang, X.*; Qian, H.*; Zhang, J.*; Ma, S.* DACH-ZYC-Phos/Pd-Catalyzed Enantioselective Allenylation of Secondary Phosphine Oxides via Ligand Relay. J. Am. Chem. Soc.2025, 147, accepted. (1: equal contribution)
12.Wang, W.; Hong, S.; He, W.; Zhang, X.*; Qian, H.*; Ma, S.* Stereoselective Rhodium-catalyzed Reaction of Allenes with Organoboronic Reagents for Diversified Branched 1,3-Alkadienes. Nat. Commun.2024, 15, 8344.
13.Wang, J.1; Zheng, W.-F.1; Zhang, X.*; Qian, H.*; Ma, S.* Stereoselectivity Control in Rh-catalyzed β-OH Elimination for Chiral Allene Formation. Nat. Commun.2023, 14, 7399. (1 equal contribution)
14.Wang, W.; Huang, D.; Yu, Y.; Qian, H.*; Ma, S.* A Modular Approach for Syntheses of Natural and Artificial Terpenoids. Angew. Chem. Int. Ed.2023, 62, e202307626.
15.Han, Y.;1 Qin, A.;1 Zhang, Q.; Zhang, X.*; Qian, H.*; Ma, S.* Rhodium-Catalyzed Dynamic Kinetic [4+2] Cycloaddition of Allene-1,3-Dienes. Angew. Chem. Int. Ed.2022, 61, e202211635. (1: equal contribution)
16.Wang, H.; Qian, H.*; Zhang, J.*; Ma, S.* Asymmetric Axially Chiral Allenyl C-P Bond Formation. J. Am. Chem. Soc.2022, 144, 12619-12626.
17.Wu, G.;1 Yao, Y.;1 Li, G.; Zhang, X.*; Qian, H.*; Ma, S.* Enantioselective Allenation of Terminal Alkynes Catalyzed by Copper Halides of Mixed Oxidation States and Its Application to the Total Synthesis of Scorodonin. Angew. Chem. Int. Ed.2022, 61, e202112427. (1: equal contribution)
18.Wang, W.;1 Yu, Y.;1 Cheng, B.; Fang, H.; Zhang, X.*; Qian, H.*; Ma, S.* Stereodefined Rhodium-catalysed 1,4-H/D delivery for Modular Syntheses and Deuterium Integration. Nat. Catal.2021, 4, 586-594. (1: equal contribution)
19.Wang, H.;1 Luo, H.;1 Zhang, Z.-M.;1 Zheng, W.-F.; Yin, Y.; Qian, H.*; Zhang, J.*; Ma, S.* Pd-Catalyzed Enantioselective Syntheses of Trisubstituted Allenes via Coupling of Propargylic Benzoates with Organoboronic Acids. J. Am. Chem. Soc.2020, 142, 9763-9771. (1: equal contribution)
20.Zheng, W.-F.; Zhang, W.; Huang, C.; Wu, P.; Qian, H.*; Wang, L.; Guo, Y.-L.*; Ma, S.* Tetrasubstituted Allenes via the Palladium Catalysed Kinetic Resolution of Propargylic Alcohols Using a Supporting Ligand. Nat. Catal.2019, 2, 997-1005.
Zhao, W.1; Qian, H.1; Li, Z.*; Sun, J.* (1: equal contribution) Catalytic Ring Expansion of Cyclic Hemiaminals for the Synthesis of Medium Ring Lactams. Angew. Chem., Int. Ed.2015, 54, 10005-10008.
Qian, H.; Zhao, W.; Wang, Z.; Sun, J.* Organocatalytic Enantio- and Diastereoselective Synthesis of 1,2-Dihydronaphthalenes from Isobenzopyrylium Ions. J. Am. Chem. Soc.2015, 137, 560-563.
Qian, H.; Zhao, W.; Sun, J.* Siloxy Alkynes in Annulation Reactions. Chem. Rec. 2014, 14, 1070-1085.
Qian, H.; Sun, J.* Organocatalytic Enantio- and Diastereoselective Assembly of Thiazolidine Scaffolds by Formal [3+2] Annulation. Asian J. Org. Chem. 2014, 3, 387-390.
Qian, H.; Yu, X.; Zhang, J.*; Sun, J.* Organocatalytic Enantioselective Synthesis of 2,3-Allenoates by Intermolecular Addition of Nitroalkanes to Activated Enynes. J. Am. Chem. Soc. 2013, 135, 18020-18023.
Qian, H.;Zhao, W.; Sung, H. H.-Y.; Williams, I. D.; Sun, J.* Stereoselective Synthesis of Aminoindanols via An Efficient Cascade aza-Michael/Aldol Reaction. Chem. Commun. 2013, 49, 4361-4363.
